__ sapiens

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Possible Answers: HOMO.

Last seen on: LA Times Crossword 22 Oct 18, Monday

Random information on the term “__ sapiens”:

Berengar, called the Wise (Catalan: Berenguer el Savi, Latin: Berengarius Sapiens), was the count (or duke) of Toulouse (814–835) and duke (or margrave) of Septimania (832–835). He held the County of Barcelona concomitantly with Septimania.

Berengar was a member of the family of the Unrochids. He was the son of Unruoch II of Friuli and Ingeltrude and brother of Eberhard. His nephew was the Holy Roman Emperor Berengar.

In 814, Louis the Pious installed Berengar as Count of Toulouse in succession to Raymond Raphinel who had been appointed by Charlemagne. He was also a councillor of Pepin I of Aquitaine in 816. In 819, he and Guerin, Count of Auvergne, fought against the usurping Duke of Gascony, Lupo III Centule. Berengar appears as a missus dominicus of Louis in May 825 and then in 827 in the six counties of Rheims, Soissons, Senlis, Beauvais, Laon, and Catolonis and the four bishoprics of Amiens, Cambrai, Saint-Pol-sur-Ternoise, and Noviomacensem.

In November 831, Pepin revolted against his father, with Berengar advising him not to rebel, but with Bernard of Septimania inciting him. In the beginning of 832, Louis the Pious began campaigning against his rebellious son. Berengar, loyal to the Emperor, attacked the domains of Bernard, taking Roussillon (with Vallespir), Razès, and Conflent. On 2 February, Berengar had already reached Elna. Finally, in the autumn of the same year, successive victories by the imperial forces compelled Pepin and Bernard to appear before the Emperor (October) to plead for peace. Pepin was dispossessed of his kingdom and sent, as a prisoner, to Trier. His territories were given to Charles the Bald, youngest son of the Emperor. Bernard was accused of infidelity and dispossessed of all his lands in Septimania and Gothia; they were given to Berengar. Gaucelm, Bernard’s brother, was also dispossessed of the majority of his lands, but for a time kept the Empúries although this too was lost to Berengar later.

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Random information on the term “HOMO”:

The Diels–Alder reaction is an organic chemical reaction (specifically, a [4+2] cycloaddition) between a conjugated diene and a substituted alkene, commonly termed the dienophile, to form a substituted cyclohexene derivative. It was first described by Otto Diels and Kurt Alder in 1928, for which work they were awarded the Nobel Prize in Chemistry in 1950. The Diels–Alder reaction is particularly useful in synthetic organic chemistry as a reliable method for forming 6-membered systems with good control over regio- and stereochemical properties.[1][2][3] The underlying concept has also been applied to other π-systems, such as carbonyls and imines, to furnish the corresponding heterocycles, known as the hetero-Diels–Alder reaction. Diels–Alder reactions can be reversible under certain conditions; the reverse reaction is known as the retro-Diels–Alder reaction.[4] it is an example of pericyclic reaction.

The reaction is an example of a concerted pericyclic reaction.[5] It is believed to occur via a single, cyclic transition state,[6] with no intermediates generated during the course of the reaction. As such, the Diels–Alder reaction is governed by orbital symmetry considerations: it is classified as a [4πS+2πS] cycloaddition, indicating that it proceeds through the suprafacial/suprafacial interaction of a 4π electron system (the diene structure) with a 2π electron system (the dienophile structure), an interaction that is thermally allowed as a 4n+2 cycloaddition.[7]

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